![]() ![]() ![]() Tetraacylgermanes are easily accessible via a one-pot synthetic protocol in >85 % yield, as confirmed by NMR spectroscopy, mass spectrometry, and X-ray crystallography. In this contribution a convenient synthetic method to obtain tetraacylgermanes Ge4 (R=mesityl (1 a), phenyl (1 b)), a previously unknown class of highly efficient Ge-based photoinitiators, is described. Judith Radebner, Anna Eibel, Mario Leypold, Christian Gorsche, Lukas Schuh, Roland Fischer, Ana Torvisco, Dmytro Neshchadin, Roman Geier, Norbert Moszner, Robert Liska, Georg Gescheidt, Michael Haas, Harald Stueger, Tetraacylgermanes: Highly Efficient Photoinitiators for Visible-Light-Induced Free-Radical Polymerization.PMID: 28156043 ( view PubMed database entry )ĭOI: 10.1002/anie.201611686 ( read at publisher's website ) ![]()
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